Jimmy Kimmel, Tems

The one and only Jimmy Kimmel from "Jimmy Kimmel Live!" stops by the show. Tems sits down for a chat and also performs "Love Me JeJe" a song from her album "Born in the Wild." Jennifer also welcomes Dr. Brian Rambarran, a urologist from Buffalo, New York, who is also a dedicated pilot. Once a month, Dr. Rambarran flies rescue missions to save animals, with a viral video of him unloading puppies garnering millions of views. For the past 12 years, he's been rescuing dogs from kill shelters and euthanasia lists in Asheville, North Carolina, and transporting them to Nickel City Canine Rescue in Buffalo. As a urological cancer surgeon, he saves lives — and he gives dogs a second chance at life, too.